全文获取类型
收费全文 | 7149篇 |
免费 | 1310篇 |
国内免费 | 1455篇 |
专业分类
化学 | 2409篇 |
晶体学 | 127篇 |
力学 | 276篇 |
综合类 | 86篇 |
数学 | 1291篇 |
物理学 | 5725篇 |
出版年
2024年 | 12篇 |
2023年 | 63篇 |
2022年 | 157篇 |
2021年 | 194篇 |
2020年 | 143篇 |
2019年 | 170篇 |
2018年 | 156篇 |
2017年 | 258篇 |
2016年 | 259篇 |
2015年 | 269篇 |
2014年 | 412篇 |
2013年 | 549篇 |
2012年 | 455篇 |
2011年 | 431篇 |
2010年 | 415篇 |
2009年 | 494篇 |
2008年 | 586篇 |
2007年 | 579篇 |
2006年 | 546篇 |
2005年 | 507篇 |
2004年 | 393篇 |
2003年 | 386篇 |
2002年 | 316篇 |
2001年 | 282篇 |
2000年 | 287篇 |
1999年 | 260篇 |
1998年 | 205篇 |
1997年 | 217篇 |
1996年 | 173篇 |
1995年 | 131篇 |
1994年 | 101篇 |
1993年 | 88篇 |
1992年 | 91篇 |
1991年 | 57篇 |
1990年 | 49篇 |
1989年 | 59篇 |
1988年 | 47篇 |
1987年 | 22篇 |
1986年 | 15篇 |
1985年 | 11篇 |
1984年 | 13篇 |
1983年 | 3篇 |
1982年 | 10篇 |
1981年 | 8篇 |
1980年 | 5篇 |
1979年 | 9篇 |
1977年 | 4篇 |
1974年 | 5篇 |
1973年 | 4篇 |
1971年 | 3篇 |
排序方式: 共有9914条查询结果,搜索用时 828 毫秒
51.
We employ an agent‐based model to show that memory and the absence of an a priori best strategy are sufficient for self‐segregation and clustering to emerge in a complex adaptive system with discrete agents that do not compete over a limited resource nor contend in a winner‐take‐all scenario. An agent starts from a corner of a two‐dimensional lattice and aims to reach a randomly selected site in the opposite side within the shortest possible time. The agent is isolated during the course of its journey and does not interact with other agents. Time‐bound obstacles appear at random lattice locations and the agent must decide whether to challenge or evade any obstacle blocking its path. The agent is capable of adapting a strategy in dealing with an obstacle. We analyze the dependence of strategy‐retention time with strategy for both memory‐based and memory‐less agents. We derive the equality spectrum to establish the environmental conditions that favor the existence of an a priori best strategy. We found that memory‐less agents do not polarize into two opposite strategy‐retention time distributions nor cluster toward a center distribution. © 2004 Wiley Periodicals, Inc. Complexity 9: 41–46, 2004 相似文献
52.
Intermolecular Interactions in 8-Aza-D-Homogonane Crystals and their Manifestation in the IR Spectra
A. A. Akhrem A. A. Govorova O. V. Gulyakevich A. S. Lyakhov A. L. Mikhal'chuk I. V. Skornyakov G. B. Tolstorozhev 《Journal of Applied Spectroscopy》2004,71(2):156-163
Crystalline modifications of 8-aza-D-homogon-1,3,5(10),13-tetraen-12,17a-dione have been investigated by IR spectroscopy and x-ray structural analysis. It is shown that this compound crystallizes from solutions of chloroform with hexane in the form of a solvate comprised of chelate hydrogen bonds between the hydrogen atom of the chloroform molecule and the oxygen atoms of the carbonyl groups of the 8-azasteroid molecule. A relation between the changes in the characteristic absorption bands of the CH2-, C=O-, and I=C groups and the structure of the crystalline modifications has been established. 相似文献
53.
M. I. Gil' 《Proceedings of the American Mathematical Society》2003,131(12):3737-3746
A linear operator in a separable Hilbert space is called a quasinormal one if it is a sum of a normal operator and a compact one. In the paper, bounds for the spectrum of quasinormal operators are established. In addition, the lower estimate for the spectral radius is derived. Under some restrictions, that estimate improves the well-known results. Applications to integral operators and matrices are discussed. Our results are new even in the finite-dimensional case.
54.
55.
F-H实验仪与光栅光谱仪连用观测253.7nm谱线 总被引:1,自引:0,他引:1
通过F-H实验仪和光栅光谱仪的连用,可实时观测汞原子从6s6s1So态激发到6s6sSP1态,退激时,辐射出能量为4.9eV的光量子,其波长为253.7nm. 相似文献
56.
The vibronic spectra of charge transfer excitons (CTE) in a molecular one-component or alternatingly ordered two-component chain are treated in the framework of a dynamic approach (neglecting thermal excitations of the intramolecular vibrations). The model introduces two mechanisms of coupling between CTEs and vibrational quanta: (1) shift of the equilibrium positions of the nuclei in the ionized donor or acceptor; (2) change of the vibrational frequency in the ionized molecule. This model allows to generalize the simple CTE Hamiltonian and the vibronic Hamiltonian of Frenkel excitons. The linear optical susceptibility is calculated in the vibronic region (one CTE and one vibrational quantum). The double splitting of vibronics of CTEs was analyzed: (1) the splitting connected with the location of the intramolecular vibration on the donors or on the acceptors; (2) the splitting connected with the symmetry of the vibronic spectra (in the degenerate case). The general structure of the vibronic spectra of CTEs is established. It contains structureless absorption lines, which correspond to two-particle bands (the phonon is excited on a neutral molecule neighboring the donor or the acceptor) and Lorentz-type lines of one-particle states, which correspond to the bound propagation of the CTE and the phonon. 相似文献
57.
Using a high resolution Raman spectrometer, we have measured Ar-broadening coefficients in the ν2Q branch of C2H2 for 22 lines at 295 K, 20 lines at 174 K, and 16 lines at 134 K. These lines with J values ranging from 1 to 23 are located in the spectral range 1970.9-1974.3 cm−1. The collisional widths are obtained by fitting each spectral line with a Rautian profile. The resulting broadening coefficients are compared with theoretical values arising from close coupling and coupled states calculations. A satisfactory agreement is obtained at room as well as at low temperatures, especially for odd J lines. By comparing broadening coefficients at 295, 174, and 134 K from a simple power law, the temperature dependence of these broadenings has been determined both experimentally, and theoretically. 相似文献
58.
It has been observed that a quantum theory need not be Hermitian to have a real spectrum. We study the non-Hermitian relativistic quantum theories for many complex potentials, and obtain the real relativistic energy eigenvalues and corresponding eigenfunctions of a Dirac-charged particle in complex statically and spherically symmetric potentials. Complex Dirac–Eckart, complex Dirac–Rosen–Morse II, complex Dirac–Scarf and complex Dirac–Poschl–Teller potential are investigated. 相似文献
59.
用激光溅射 分子束技术研究了气相中Ni的等离子体与甲醇分子团簇的反应 .观察到Ni+ (CH3 OH) n、NiO+ (CH3 OH) n、H+ (CH3 OH) n、H3 O+ (CH3 OH) n 四个种类的团簇正离子和CH3 O-(CH3 OH) n(n≤ 2 5 )一种团簇负离子 .详细考察了激光烧蚀等离子体作用于脉冲分子束的不同位置时 ,对团簇产物种类和团簇尺寸大小的影响 .发现NiO+ (CH3 OH) n 是由Ni+ (CH3 OH) n 团簇内的脱甲烷反应生成的 ,而H+ (CH3 OH) n、H3 O+ (CH3 OH) n主要是激光等离子体中的电子与甲醇团簇碰撞电离产生的 相似文献
60.
给出了低阻抗二极管产生的电子束能谱分布及外加磁场对二极管阻抗影响的数值模拟研究结果。结果表明,即使在外加电压恒定的条件下,二极管产生的电子束也具有一定的能谱分布,这说明用二极管电压、电流波形计算脉冲电子束能谱分布是不正确的。另外,外加磁场对低阻抗二极管的阻抗特性具有较大影响,其阻抗随外加磁场的增大而减小。分析认为这是由于外加磁场强度的变化改变了二极管中束电子的运动轨迹。当没有外加磁场或外加磁场较小时,低阻抗二极管产生的电子束发生自箍缩,此时二极管电流是自箍缩饱和顺位流;当外加磁场足够强时,电子束的自箍缩被抑制,二极管电流是没有箍缩时的空间电荷限制电流。束电流小于自箍缩临界电流的二极管其阻抗将不随外加磁场的变化而变化。 相似文献